Gas permeation properties through Al-doped organosilica membranes with controlled network size

作者：Kanezashi Masakoto^*; Miyauchi Shuji; Nagasawa Hiroki; Yoshioka Tomohisa; Tsuru Toshinori

来源：Journal of Membrane Science, 2014, 466: 246-252.

DOI：10.1016/j.memsci.2014.04.051

• Organosilica
• Membrane
• Gas permeation properties
• Metal doping
• Pore size

The sal-gel method was applied to the fabrication of Al-doped bis (triethoxysilyl) methane (BTESM)derived membranes. The single-gas permeation properties for Al-doped BTESM-derived membranes were examined to evaluate the effect of aluminum concentration on amorphous silica network sizes. Each permeance was decreased with an increase in the Al concentration, and the H-2/CH4 and H-2/C3H8 permeance ratios increased with an increase in Al concentration. For example, an Al-doped BTESM (Si/Al= 8/2) membrane fabricated at 200 degrees C showed a H-2 permeance of 4.4 x 10(-7) mol m(-2) s(-1) Pa-1, which was approximately 1/10th that of a BTESM membrane fabricated at 200 degrees C. The H-2/CH4 and H-2/C3H8 permeance ratios were 60 and 2700 with Al doping, but 30 and 1000 without Al-doping, respectively. The activation energy of He, H-2, N-2, and CH4 permeation was increased with an increase in the Al concentration, indicating that the pore size of BTESM-derived networks was decreased with an increase in Al concentration. The decrease in BTESM-derived network sizes that resulted from an increase in the Al concentration can be ascribed to the absolute amount of Al incorporated into BTESM-derived networks and/or coordinated with Si-OH groups, as suggested by Al-27 MAS NMR. High C3H6/C3H8 permeance ratios of approximately 40 for Al-doped BTESM (Si/Al=9/1) membranes fabricated at 200 degrees C were achieved through the precise control of the silica network size via a spacer method using Si-C-Si units as well as the incorporation of Al in BTESM-derived networks.

• 出版日期2014-9-15