科研之友
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摘要
A synthetic approach combining hydrothermal and ionothermal (eutectic mixture of choline chloride and malonic acid) procedures is proposed that allowed the isolation of the first lanthanide-organic frameworks with residues of 1,4-phenylenebis(methylene)diphosphonic acid (H(4)pmd), [Ln(Hpmd)(H2O)] (where Ln(3+) = Ce3+ and Pr3+), exhibiting an unprecedented trinodal topology with 3- and 8-connected nodes. The structural details were unveiled front singale-crystal X-ray diffraction and the materials were characterized using standard techniques.
- 出版日期2008-11
