科研之友
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摘要
We report an efficient enantioselective conjugate addition of photogenerated alpha-amino radicals to Michael acceptors catalyzed by a newly prepared chiral-at-metal rhodium complex. This protocol shows that a single Rh(III) complex can serve not only as a Lewis acid but also as a photoredox catalyst to control the stereoselectivity during the bond formation.
- 出版日期2017-7-11
- 单位中国科学院福建物质结构研究所
