科研之友
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摘要
We report the first example of a palladium-catalyzed decarboxylative dearomatization reaction that occurs via Pd-pi-benzyl intermediates. In fact, the Pd-catalyzed decarboxylative cross-coupling reaction of benzyl enol carbonates can lead to either the dearomatized alicyclic ketones or alpha-monoarylated ketone products depending on the catalyst and ligand employed.
- 出版日期2016
