Non-innocence of beta-diketiminato ligands

作者：Gondzik S; Blaeser D; Woelper C; Schulz S^*

来源：Journal of Organometallic Chemistry, 2015, 783: 92-95.

DOI：10.1016/j.jorganchem.2015.02.028

• Zinc
• beta-Diketiminate
• Sulfur

The homoleptic thio-beta-ketiminate zinc complex [MesNC(Me)CH{C(Me)NMes}S](2)Zn (1) was obtained from reactions of elemental sulfur with the beta-diketiminato zinc complexes [CH{C(Me)NMes}(2)]ZnMe, [CH {C(Me)NMes}(2)](2)Zn-2 and [[CH{C(Me)NMes}(2)]Zn-TePh](2). 1 and the byproducts were characterized by multinuclear NMR (H-1, C-13, Te-125) and IR spectroscopy, elemental analyses as well as by single crystal X-ray diffraction.

• 出版日期2015-5-1