A shock tube study of cyclopentane and cyclohexane ignition at elevated pressures

作者:Daley Shane M; Berkowitz Andrew M; Oehlschlaeger Matthew A*
来源:International Journal of Chemical Kinetics, 2008, 40(10): 624-634.
DOI:10.1002/kin.20353

摘要

Ignition delay times for cyclopentane/air and cyclohexane/air mixtures were measured in a shock tube at temperatures of 847-1379 K, pressures of 11-61 atm, and equivalence ratios of phi = 1.0, 0.5, and 0.25. Ignition times were determined using electronically excited OH emission monitored through the shock tube endwall and piezoelectric pressure measurements made in the shock tube sidewall. The dependence of ignition time on pressure, temperature, and equivalence ratio is quantified and correlations for ignition time formulated. Measured ignition times are compared to kinetic modeling predictions from four recently published mechanisms.

  • 出版日期2008-10