Low-temperature-selective luminescent mechanochromism of a thienyl gold isocyanide complex

作者:Seki Tomohiro; Kobayashi Koh; Ito Hajime
来源:Chemical Communications, 2017, 53(50): 6700-6703.
DOI:10.1039/c7cc03190d

摘要

The low-temperature-selective mechanochromism of a thienyl gold(I) isocyanide complex is reported. The as-prepared powder of this complex did not show any luminescent color changes upon grinding at room temperature. When cooled below -50 degrees C, the powder showed a blue emission in the absence of a phase transition. Upon grinding this powder below -50 degrees C, a green emission was observed, which indicates notable mechanochromism that only occurs at low temperature.

  • 出版日期2017-6-25