Development of a Molecularly Imprinted Electrochemical Sensor for Tert-Butylhydroquinone Recognition

作者:Qin, Rongzhou; Wang, Qilin; Ren, Chaoqin; Dai, Xianzhi; Han, Haijun*
来源:International Journal of Electrochemical Science, 2017, 12(10): 8953-8962.
DOI:10.20964/2017.10.04

摘要

In this work, a new molecularly imprinted voltammetric sensor was fabricated based on a glassy carbon electrode (GCE) modified with reduced graphene oxide (rGO)-based silver nanoparticles (AgNPs) for the detection of tert-butylhydroquinone (TBHQ). X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) techniques were used for the characterization of the proposed surfaces. The linearity range of the proposed method was determined to be 0.05-1.5 nM, and the limit of detection (LOD) was 1.48 x 10(-11) M. The new voltammetric sensor exhibited remarkable recovery and selectivity for the detection of real specimens. The stability of the sensor was also investigated.

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