A New Type of Three-Dimensional Hybrid Polymeric Haloplumbate Based on Rare High-Nuclear Heterometallic Clusters

作者：Zhou, Jian^*; Xiao, Hong; Zou, Hua-Hong^*; Liu, Xing

来源：Inorganic Chemistry, 2018, 57(20): 12860-12868.

DOI：10.1021/acs.inorgchem.8b02069

• TRANSITION-METAL COMPLEX
• TITANIUM OXO CLUSTERS
• CRYSTAL-STRUCTURES
• LEAD HALIDE
• MAGNETIC SEMICONDUCTOR
• STRUCTURAL CHEMISTRY
• IODOPLUMBATE
• AG
• PEROVSKITES
• FRAMEWORKS

A series of new three-dimensional hybrid heterometallic haloplumbates [Pb8M(mu(3)-O)(2)X-8(XH)(eg)(3)](n) {H(2)eg = ethylene glycol; X = Cl, M = Co (1a), Ni (1b), Zn (1c); X = Br, M = Ni (2a), Zn (2b); X = I, M = Zn (3)} have been solvothermally synthesized and structurally characterized. Compounds 1a-c, 2a-b, and 3 consist of one-dimensional haloplumbate [Pb2X9] chains, and heptanuclear heterometallic [Pb6M(mu(3)-O)(2)(eg)(3)] clusters based on two [Pb-3(mu(3)-O)(eg)(1.5)] cores share one M2+ ion, which are interconnected to generate three-dimensional heterometallic frameworks. Although a few heterometallic haloplumbates incorporating other metal complexes have been reported, they usually exhibit low-dimensional structures. The present heterometallic haloplumbates offer good examples of applying high-nuclear heterometallic [Pb6MO2(eg)(3)] clusters to construct a new type of high-dimensional hybrid heterometallic haloplumbate. Compounds 1a-b and 2a indicate unusual ferrimagnetic behavior. Their optical properties are investigated at room temperature, and density functional theory calculations of compounds 1c, 2b, and 3 are also studied.

• 出版日期2018-10-15
• 单位重庆师范大学; 广西师范大学