A novel copper containing photoinitiator, copper(II) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization

作者：Gong Tao; Adzima Brian J; Bowman Christopher N^*

来源：Chemical communications, 2013, 49(72): 7950-7952.

DOI：10.1039/c3cc43637c

A novel copper(II) complex has been developed in which the counter anion, acylphosphinate, serves as a visible light photoinitiator. This molecule is inactive in the dark but, upon visible light exposure, both CuAAC and ATRP reactions are readily and rapidly initiated.

• 出版日期2013