科研之友
微信
新浪微博
Facebook
分享链接
摘要
A computer simulation program including the principle of (1) mass transport, (2) current density distribution, (3) energy consumption and (4) limiting current density is developed for predicting desalinating performance of a continuous (one-pass flow) electrodialysis process. in this simulation the following parameters are inputted; (1) membrane characteristics such as overall transport number, overall solute permeability, overall electro-osmotic permeability, overall hydraulic permeability, direct current electric resistance etc. (2) electrodialyzer specifications such as flow-pass thickness, flow-pass width and flow-pass length of a desalting cell etc. and (3) electrodialytic conditions such as current density, electrolyte concentration in a feeding solution, linear velocity in desalting cells, standard deviation of normal distribution of solution velocity ratio etc. In a practical-scale electrodialyzer, electrolyte concentration in a desalting cell is decreased along a flow-pass and it gives rise to electrolyte concentration distribution. It causes electric resistance distribution and current density distribution. Solution velocities in desalting cells vary between the cells, and give rise to solution velocity distribution. In this simulation, these distributions are taken into account assuming that the frequency distribution of solution velocity ratio is equated by the normal distribution. Further, the influences of electrodialyzer specifications and elctrodialysis conditions described above on the performances of an electrodialyzer (desalting ratio, current efficiency, electrolyte concentration at the outlets of desalting cells, cell voltage, energy consumption, electrolyte concentration distribution. current density distribution, and limiting current density) are predicted. The simulation model is developed on the basis of the experiments and its reasonability is supported by the performance of electrodialyzers operating in salt-manufacturing plants.
- 出版日期2009-12-15
