科研之友
微信
新浪微博
Facebook
分享链接
摘要
An 18-membered complex, [Fe(MMSHZ)(DMF)]6 (1) [MMSHZ = N-(methyl-maleamic ester)acylsalicyl-hydrazine] was synthesized and structurally characterized. There are not only particular geometry configurations of N-terminal groups which result in the unique shape of the centric cavity, but also inter- and intra-molecular interactions assembling adjacent molecules into 2-D framework in complex 1. Temperature-dependent magnetic susceptibility measurements indicate that this complex exhibits significantly antiferromagnetic coupling among the metal centers.
