Development of a field sampling method based on magnetic nanoparticles for the enrichment of pesticides in aqueous samples

作者：Zhang, Lingyi; Sheng, Xiaoling; Zhang, Runsheng^*; Xiong, Zhichao; Wu, Zhongping; Yan, Songmao; Zhang, Yurong; Zhang, Weibing

来源：Analyst, 2014, 139(23): 6279-6283.

DOI：10.1039/c4an01469c

• SOLID-PHASE EXTRACTION
• CHROMATOGRAPHY-MASS SPECTROMETRY
• BAR SORPTIVE EXTRACTION
• ORGANOCHLORINE PESTICIDES
• MICROEXTRACTION SPME
• ORGANIC-COMPOUNDS
• GC-MS
• SPE
• DEVICE
• PRECONCENTRATION

A field sampling method based on magnetic core-shell silica nanoparticles was developed for field sampling and the enrichment of low concentrations of pesticides in aqueous samples. The magnetic nanoparticles could be easily extracted from water samples by a custom-made magnetic nanoparticle collector. The recovery of 15 mg of magnetic particles from a 500 mL water sample was 90.8%. Mixtures of seven pesticides spiked into pure water and pond water were used as marker samples to evaluate the field sampling method. The average recoveries at three levels of spiking were in the range 60.0-104.7% with relative standard deviations <7.1%. The proposed method has good linearity with a correlation coefficient >0.9990 in the concentration range 0.5-15 mu g L-1. The results of the analysis of a sample of poisoned pond water indicate that this method is fast, convenient and efficient for the field sampling and enrichment of pesticides in aqueous samples.

• 出版日期2014
• 单位司法部司法鉴定科学技术研究所; 华东理工大学