Aminopropyltrimethoxysilane-functionalized boron nitride nanotube based epoxy nanocomposites with simultaneous high thermal conductivity and excellent electrical insulation

作者：Zhang, Chi; Huang, Rongjin^*; Wang, Yongguang; Wu, Zhixiong; Guo, Shibin; Zhang, Hua; Li, Jian; Huang, Chuanjun; Wang, Wei; Li, Laifeng^*

来源：Journal of Materials Chemistry A, 2018, 6(42): 20663-20668.

DOI：10.1039/c8ta07435f

• GRAPHITE NANOPLATELET
• POLYMER COMPOSITES
• CARBON NANOTUBES
• INTERFACE
• SOLUBILIZATION
• PERFORMANCE
• TRANSPORT

Insulating polymeric materials with excellent thermal and dielectric properties are highly promising for thermal management applications in future energy systems. However, a well-acknowledged problem is that traditional polymeric composites usually suffer from either low thermal transfer efficiency or high dielectric loss, failing to meet the requirements for simultaneous properties of high thermal conductivity and high electrical insulation. In this work, utilizing aminopropyltrimethoxysilane-functionalized boron nitride nanotubes (BNNT-APS) as fillers, an ideal dielectric epoxy nanocomposite is successfully fabricated. At a low BNNT loading of 10 wt%, the nanocomposites demonstrate a 650% thermal conductivity enhancement at both room temperature and cryogenic temperatures with the preservation of a low dielectric constant and dielectric loss. In addition, a 20% reduction of the coefficient of thermal expansion (CTE) at cryogenic temperatures is achieved at the same time. The superiority of the designed nanocomposites is suggested to stem from the outstanding intrinsic properties of BNNTs, effective surface modification by APS molecules, and low interfacial thermal resistance.

• 出版日期2018-11-14
• 单位中国科学院理化技术研究所; 中国科学院大学