Arsenic-Mediated C-C Coupling of Cyanides Leading to Cyanido Arsazolide [AsC4N4](-)

作者：Arlt Soeren; Harloff Joerg; Schulz Axel^*; Stoffers Alrik; Villinger Alexander

来源：Chemistry - A European Journal, 2017, 23(52): 12735-12738.

DOI：10.1002/chem.201703317

• arsenic
• C-C coupling
• cyanides
• isomerization
• heterocycles

The chemistry of arsenic cyanides has been investigated and is found to be completely different to the chemistry of the heavier analogs antimony and bismuth as well as phosphorus. The reaction of As(CN)(3) with cyanide salts resulted in the formation of an unknown cyanido arsazolide heterocycle, which represents a structure isomer of the desired [As(CN)(4)](-). The structure, bonding, and formation of this unusual heterocycle is discussed featuring an arsenic mediated C-C coupling of cyanides. [AsC4N4](-) salts with different counterions such as [PPh4](+), [PPN](+) =[Ph3P-N-PPh3](+), Ag+, and [BMIm](+) are reported with [BMIm][AsC4N4] being a low-temperature ionic liquid (T-m= -628 degrees C).

• 出版日期2017-9-18