Direct Arylation of Pyrroles via Indirect Electroreductive C-H Functionalization Using Perylene Bisimide as an Electron-Transfer Mediator

作者：Sun, Guoquan; Ren, Shuya; Zhu, Xinhai^*; Huang, Manna; Wan, Yiqian

来源：Organic Letters, 2016, 18(3): 544-547.

DOI：10.1021/acs.orglett.5b03581

• ORGANIC ELECTROSYNTHESIS
• CARBON CATHODES
• ANION-RADICALS
• ARYL HALIDES
• REDUCTION
• WATER
• BOND
• CYCLIZATION
• CHEMISTRY
• CHLORIDES

The indirect electroreductive coupling of aryl halides and pyrroles was successfully conducted using a catalytic amount of perylene bisimide as a mediator in 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide ([EMIM]NTf2)/DMSO.

• 出版日期2016-2-5
• 单位中山大学