Tolyporphin-An Unusual Green Chlorin-like Dioxobacteriochlorin

作者:Bruckner Christian*
来源:Photochemistry and Photobiology, 2017, 93(5): 1320-1325.
DOI:10.1111/php.12787

摘要

The tolyporphins, a family of green tetrapyrrolic pigments isolated from a cyanobacterium-microbial ecological unit, possess unique carbohydrate-derivatized dioxobacteriochlorin frameworks. A brief overview over the history, synthesis, chemistry and biological properties of the tolyporphins forms the backdrop for highlighting the contribution by Hood et al. (Photochem. Photobiol., 2017, ) who demonstrate the optical properties of tolyporphins to be more similar to those of chlorins than of bacteriochlorins. This property could be correlated with the presence of -oxo-functionalities. The study continues to clarify the structure, properties and possible roles of these intriguing chromophores with a range of biomedical properties.

  • 出版日期2017-10