Maghemite nanorods anchored on a 3D nitrogen-doped carbon nanotubes substrate as scalable direct electrode for water oxidation

作者：Sharifi Tiva; Kwong Wai Ling; Berends Hans Martin; Larsen Christian; Messinger Johannes; Wagberg Thomas

来源：International Journal of Hydrogen Energy, 2016, 41(1): 69-78.

DOI：10.1016/j.ijhydene.2015.11.165

• Nitrogen-doped carbon nanotubes
• Maghemite
• Hybrid catalyst
• Water oxidation
• 3D electrode

A hybrid catalyst 3D electrode for electrochemical water oxidation to molecular oxygen is presented. The electrode comprises needle shaped maghemite nanorods firmly anchored to nitrogen doped carbon nanotubes, which in turn are grown on a conducting carbon paper that acts as efficient current collector. In 0.1 M KOH this hybrid electrode reaches a current density of 1 mA/cm(2) (geometric surface) at an overpotential of 362 mV performing high chronoamperometric stability. The electrochemical attributes point toward efficient catalytic processes at the surface of the maghemite nanorods, and demonstrate a very high surface area of the 3D electrode, as well as a firm anchoring of each active component enabling an efficient charge transport from the surface of the maghemite rods to the carbon paper current collector. The latter property also explains the good stability of our hybrid electrode compared to transition metal oxides deposited on conducting support such as fluorine doped tin oxide. These results introduce maghemite as efficient, stable and earth abundant oxygen evolution reaction catalyst, and provide insight into key issues for obtaining practical electrodes for oxygen evolution reaction, which are compatible with large scale production processes.

• 出版日期2016-1-5