A Ni-containing decaniobate incorporating organic ligands: synthesis, structure, and catalysis for allylic alcohol epoxidation

作者：Li, Li; Niu, Yanjun; Dong, Kaili; Ma, Pengtao; Zhang, Chao; Niu, Jingyang^*; Wang, Jingping^*

来源：RSC Advances, 2017, 7(46): 28696-28701.

DOI：10.1039/c7ra03254d

• HYDROGEN-PEROXIDE
• PHOTOCATALYTIC PROPERTIES
• POLYOXONIOBATE CLUSTER
• FRAMEWORK MATERIALS
• MAGNETIC-PROPERTIES
• EVOLUTION ACTIVITY
• CRYSTAL-STRUCTURE
• POLYOXOMETALATE
• HETEROPOLYNIOBATES
• OXIDATION

An organic-inorganic hybrid polyoxoniobate, Na-8{Ni[ Ni(en)](2)Nb10O32}$ 28H(2)O (1) (en = ethanediamine), has been synthesized and characterized. It represents the first example of a trinuclear nickel- containing polyoxoniobate. The catalysis of 1 for allylic alcohol epoxidation was investigated at room temperature in aqueous solution, and was found to catalyze the epoxidation of 3- methyl- 2- buten- 1- ol with high conversion (98%) and selectivity (94%). Furthermore, magnetic measurements showed that the compound exhibits ferromagnetic interactions.

• 出版日期2017
• 单位河南大学