Facile one-pot synthesis of hexagons of NaSrB5O9: Tb3+ phosphor for solid-state lighting

作者：Ramesh B; Dillip G R^*; Raju B Deva Prasad; Somasundaram K; Peddi Siva Prasad; dos Anjos Virgilio de Carvalho; Joo S W

来源：Materials Research Express, 2017, 4(4): 046201.

DOI：10.1088/2053-1591/aa6865

• borate phosphor
• rietveld refinement
• x-ray photoelectron spectroscopy
• quantum yield

NaSrB5O9: Tb3+ hexagons were synthesized by a facile solid-state reaction method. The synthesized powders were structurally examined by x-ray diffraction analysis (XRD), and Rietveld refinement was performed using the XRD data and Fullprof software. Hexagon-like morphology was observed using field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). The elemental composition of the phosphors was investigated qualitatively by energy dispersive x-ray analysis (EDS) and quantitatively by x-ray photoelectron spectroscopy (XPS). The phosphor has a strong green emission at 545 nm under excitation of 379 nm, which is due to the D-5(4) -> F-7(5) transition of the Tb3+ ion. A lifetime of 3.48 ms was obtained for the phosphor. The important parameters of the light source were determined, such as the thermal quenching, critical distance, the nature of the dopant ion interaction, color coordinates, and quantum yield values. Other reported properties include the site occupancy of the dopant, surface properties, morphological properties, and optical properties.

• 出版日期2017-4