An unusual 3D complex showing 5,8-connected topology with encapsulated 8-connected octamolybdate polyoxoanions

作者：Wang Wenju; Xu Lin^*; Gao Guanggang; Li Fengyan; Liu Xizheng; Liu Li

来源：Inorganic Chemistry Communications, 2009, 12(9): 875-878.

DOI：10.1016/j.inoche.2009.07.001

• Polyoxometalare
• Organic-inorganic hybrid
• Octamolybdate
• Topochemistry

An unprecedented inorganic-organic framework, containing octamolybdate polyoxoanions as 8-connected nodes, defines a new 5,8-connected topology and represents 8-fold interpenetrated srs (SrS(2)) topological Cu(I)-organic secondary network for the first time. While the free bipy ligand displays weak luminescence in the solid state at room temperature, this compound exhibits an intense yellow radiation emission maximum at lambda approximate to 567 nm upon excitation at lambda approximate to 365 nm.

• 出版日期2009-9
• 单位东北师范大学; 白城师范学院