科研之友
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摘要
A convergent radical based mute to azaindanes is described, relying on the degenerative addition transfer of various substituted S-(pyridylmethyl)-O-ethyl dithiotcarbonates (xanthates)' to functional,alkenes followed by radical cyclization onto the pyridine ring activated 'by protonation with-trifluoroacetic acid. In one case, a richly decorated cyclohepta[b]pyridine could be assembled swiftly by allowing the first adduct to N-pberrAinaleimide to undergo addition to.N-allylPhthalimide prior to cyclization.
- 出版日期2017-7-21
