A new perspective on the electron transfer: recovering the Butler-Volmer equation in non-equilibrium thermodynamics

作者:Dreyer Wolfgang; Guhlke Clemens; Mueller Ruediger
来源:Physical Chemistry Chemical Physics, 2016, 18(36): 24966-24983.
DOI:10.1039/c6cp04142f

摘要

Butler–Volmer equations can be recovered from a complete non-equilibrium thermodynamic model by application of asymptotic analysis. Thereby we gain insight into the coupling of different physical phenomena and can derive Butler–Volmer equations for very different materials and electrochemical systems.

  • 出版日期2016-9-28