A 3D Coordination Polymer of Sm(III) Using Inorganic Sulphate and Organic Succinate Building Blocks

作者：Manna Subal Chandra^*; Mistri Soumen; Zangrando Ennio

来源：Acta Chimica Slovenica, 2013, 60(1): 5-S10.

• Coordination polymer
• Hydrothermal synthesis
• Samarium(III)
• Succinate
• Sulphate

A lanthanide coordination polymeric network, [Sm-2 (suc)(2)(SO4)(H2O)(2)](n) (1) (suc = succinate dianion), incorporating both organic succinate and inorganic sulphate building blocks, has been synthesized and characterized by single crystal X-ray diffraction analysis. The complex displays a 3D architecture with two crystallographic independent samarium(III) ions having a distorted capped square antiprismastic geometry with O-9 donor set realized by six oxygen atoms from succinate, two from symmetry related sulphate anions and one from an aqua ligand.

• 出版日期2013