VO2 (A)/graphene nanostructure: Stand up to Na ion intercalation/deintercalation for enhanced electrochemical performance as a Na-ion battery cathode

作者：Hu, Xinyuan; Zhao, Zhengjing; Wang, Lin; Li, Jingbo^*; Wang, Chengzhi; Zhao, Yongjie; Jin, Haibo^*

来源：Electrochimica Acta, 2019, 293: 97-104.

DOI：10.1016/j.electacta.2018.10.010

• Na-ion battery
• VO2 (A) nanowire
• VO2 (A)/graphene composite
• Battery cathode material
• Cycle stability

Intercalation/deintercalation of large size Na ion leads to serious electrode materials fragmentation that would be the main reason of Na-ion battery capacity fading. Herein, we reported a Na-ion battery cathode material composed of layer-structured VO2 (A) nanowires wrapped with graphene. The VO2 (A)/graphene nanostructure which effectively suppressed pulverization of VO2 (A) nanowires during cyclic charging and discharging exhibited prominent cycle stability and high specific capacity. A reversible capacity of 115 mA h g(-1) was retained over 100 cycles at a high current density of 100 mA g(-1). Comparing to the electrochemical performance of other vanadium oxides, VO2 (A)/graphene demonstrates a potential cathode material for Na-ion batteries.

• 出版日期2019-1-10
• 单位北京理工大学