Applications of the in situ Propargyl-Allenyl Isomerization in Organic Synthesis

作者：Xing Yanpeng; Wei Yuxiu; Zhou Hongwei^*

来源：Current Organic Chemistry, 2012, 16(13): 1594-1608.

• Propargyl-allenyl isomerization
• Allene
• Cyclization
• Base-promotion

Allenes have been shown to be versatile building blocks in organic synthesis. However, the diversity of the allene chemistry offers a challenging and exquisite task for organic chemists bent on building the suitable allene substrates. A good solution might be propargyl-allenyl isomerization, which means to prepare readily available propargyl substrates. This review focuses on recent progress in the in situ propargyl-allenyl isomerization in organic synthesis, published in 1990 and later.

• 出版日期2012-7
• 单位浙江大学