科研之友
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摘要
The two criteria of ensemble equivalence, i.e., macrostate equivalence and measure equivalence, are investigated for a general pair of states. Macrostate equivalence implies the two ensembles are indistinguishable by the measurement of macroscopic quantities obeying the large-deviation principle, and measure equivalence means that the specific relative entropy of these two states vanishes in the thermodynamic limit. It is shown that measure equivalence implies a macrostate equivalence for a general pair of states by deriving an inequality connecting the large-deviation rate functions to the specific relative Renyi entropies. The result is applicable to both quantum and classical systems. As applications, a sufficient condition for thermalization, the time scale of quantum dynamics of macrovariables, and the second law with strict irreversibility in a quantum quench are discussed.
- 出版日期2016-8-5
