1D water chain stabilized by meso-expanded calix[4]pyrrole

作者:Kumar B Sathish*; Panda Pradeepta K
来源:CrystEngComm, 2014, 16(37): 8669-8672.
DOI:10.1039/c4ce01502a

摘要

A new core expanded calix[4]pyrrole is reported, in which the opposite bridging sp(3)-carbons are replaced by ethylene moieties. This macrocycle forms a unique helical pattern and binds to two water molecules, forming an infinite 1D chain synergistically stabilized through hydrogen bonding with the two outwardly projected pyrrolic NHs of the calixpyrrole.

  • 出版日期2014