An unusual involvement of NaIO4 in the acetsrlation of bisphenol during attempted oxidative acetylation

作者：Singh Deepak; Deota Pradeep T^*

来源：Tetrahedron Letters, 2013, 54(51): 7053-7055.

DOI：10.1016/j.tetlet.2013.10.072

• Bisphenols
• Bis-cyclohexadienone
• Oxidative acetylation
• Acetylation
• Bis-triquinane

An unexpected behaviour of compilation of reagent sodium metaperiodate in acetic anhydride for acetylation of bisphenols was observed during attempted oxidative acetylation of bisphenols for the synthesis of a bis-acetoxy cyclohexadienone. The products were characterized by their spectral and analytical data and a probable mechanism for acetylation involving role of NaIO4 is proposed.

• 出版日期2013-12-18