Unmasked Acyl Anion Equivalent from Acid Chloride with Indium: Reversed-Polarity Synthesis of Unsymmetric Aryl Aryl and Alkenyl Aryl Ketone through Palladium-Catalyzed Cross-Coupling Reaction

作者：Lee Dohyung; Ryu Taekyu; Park Youngchul; Lee Phil Ho^*

来源：Organic Letters, 2014, 16(4): 1144-1147.

DOI：10.1021/ol500003g

A reversed-polarity synthetic method of a range of unsymmetric aryl aryl and alkenyl aryl ketones has been developed through Pd-catalyzed cross-coupling reaction of acylindium reagents generated in situ from easily available acid chlorides and indium with various electrophiles such as aryl iodide and triflate and alkenyl triflate.

• 出版日期2014-2-21