Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase

作者：Gross Johannes^*; Tauber Katharina; Fuchs Michael; Schmidt Nina G; Rajagopalan Aashrita; Faber Kurt; Fabian Walter M F; Pfeffer Jan; Haas Thomas; Kroutil Wolfgang

来源：Green Chemistry, 2014, 16(4): 2117-2121.

DOI：10.1039/c3gc41855c

The oxidation of the renewable diols isosorbide and isomannide was successfully achieved using a TEMPO/laccase system. Furthermore, various TEMPO-derivatives were tested leading to conversions of up to %26gt;99% for the oxidation of isosorbide, isomannide, indanol and a halohydrin to the corresponding ketone.

• 出版日期2014