Nitrogen-Doped TiO2-C Composite Nanofibers with High-Capacity and Long-Cycle Life as Anode Materials for Sodium-Ion Batteries

作者：Nie, Su; Liu, Li^*; Liu, Junfang; Xie, Jianjun; Zhang, Yue; Xia, Jing; Yan, Hanxiao; Yuan, Yiting; Wang, Xianyou

来源：Nano-Micro Letters, 2018, 10(4): 71.

DOI：10.1007/s40820-018-0225-1

• Nanofibers
• Anode materials
• Sodium-ion batteries
• Pseudocapacitance
• Nitrogen-doping

Nitrogen-doped TiO2-C composite nanofibers (TiO2/N-C NFs) were manufactured by a convenient and green electrospinning technique in which urea acted as both the nitrogen source and a pore-forming agent. The TiO2/N-C NFs exhibit a large specific surface area (213.04 m(2) g(-1)) and a suitable nitrogen content (5.37 wt%). The large specific surface area can increase the contribution of the extrinsic pseudocapacitance, which greatly enhances the rate capability. Further, the diffusion coefficient of sodium ions (DNa+) could be greatly improved by the incorporation of nitrogen atoms. Thus, the TiO2/N-C NFs display excellent electrochemical @@@ [GRAPHICS] @@@ properties in Na-ion batteries. A TiO2/N-C NF anode delivers a high reversible discharge capacity of 265.8 mAh g(-1) at 0.05 A g(-1) and an outstanding long cycling performance even at a high current density (118.1 mAh g(-1)) with almost no capacity decay at 5 A g(-1) over 2000 cycles. Therefore, this work sheds light on the application of TiO2-based materials in sodium-ion batteries.

• 出版日期2018-10
• 单位南开大学; 湘潭大学