A hexanuclear iodoargentate(I) cluster of the coplanar dicubane-like type: Structure and nonlinear optical (NLO) properties of {[(t-Bu)(4)N](2)[Ag6I8]}(n)

作者：Li, Y.^*; Zhang, Z. X.; Li, K. C.; Song, W. D.; Huang, F.; Li, S. D.; Li, X. W.; Xu, J. Q.; Pan, L. Y.

来源：Polish Journal of Chemistry, 2006, 80(9): 1533-1539.

• iodoargentate(I) cluster
• dicubane-like
• structure
• nonlinear optical properties

A polynuclear silver(I) complex {[(t-Bu)(4)N](2)[Ag6I8]}(n) 1 with iodo-bridging ligands has been prepared, the centrosymmetric cluster anion can be described as two [Ag4I4] distorted cubane units sharing one [Ag2I2] plane. This cluster polymer shows strong third-order nonlinear optical (NLO) absorption and refraction with absorption coefficient alpha(2) = 8.9 x 10(-10) m(.)w(-1) and refractive index n(2) = -6.6 x 10(-17) m(2 .)w(-1).

• 出版日期2006-9
• 单位吉林大学; 广东海洋大学