Deprotection of 1,1-diacetates with [NO+ center dot crown center dot H(NO3)(2)(-)]

作者：Zolfigol MA^*; Zebarjadian MH; Mohammadpoor Baltork I; Shamsipur M

来源：Synthetic Communications, 2002, 32(18): 2803-2808.

DOI：10.1081/SCC-120006463

An ionic complex has been obtained from N2O4 in the presence of the macrocyclic polyether 18-crown-6. This crystalline compound was used as an effective deprotecting agent for the conversion of 1,1-diacetates to their corresponding aldehydes at room temperature with quantitative yields.

• 出版日期2002