Anion dependent silver(I) complexes of pyrazine mono-N-oxide

作者:Puttreddy Rakesh; Cottam Justine R A; Steel Peter J*
来源:RSC Advances, 2014, 4(43): 22449-22454.
DOI:10.1039/c4ra01336k

摘要

Pyrazine mono-N-oxide shows a clear preference for coordination to silver( I) through the nitrogen atom. However, in some cases it acts as an N,O-bridging ligand to form 1D coordination polymers. The specific species formed is dependent on the nature of the counteranion. In general, the complexes formed have additional weak interactions that appear to control the crystal packing.

  • 出版日期2014