A novel asymmetric hydroarsination reaction promoted by a chiral organopalladium complex

作者：Bungabong Maricar L; Tan Kien Wee; Li Yongxin; Selvaratnam Selvasothi V; Dongol Krishna G; Leung Pak Hing^*

来源：Inorganic Chemistry, 2007, 46(11): 4733-4736.

DOI：10.1021/ic0701561

The dissymmetrical chiral bidentate (R)-(+)-1-(diphenylphosphino)-2-(diphenylarsino)propane was prepared stereoselectively via the novel asymmetric hydroarsination reaction between diphenylarsine and diphenyl-1-propenyl-(E)-phosphine using di-mu-chlorobis{(S)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N}dipalladium(II) as the chiral reaction promoter.

• 出版日期2007-5-28
• 单位南阳理工学院