A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

作者：Sunatsuki Yukinari; Kishima Yukana; Kobayashi Tamami; Yamaguchi Tomoka; Suzuki Takayoshi; Kojima Masaaki^*; Krzystek J; Sundberg Markku R

来源：Chemical communications, 2011, 47(32): 9149-9151.

DOI：10.1039/c1cc12418h

A series of mononuclear Mn-II, Mn-III, and Mn-IV complexes was prepared using a single tripodal ligand (H3L). Addition of a cation (NH4+, K+, Na+) to [(MnL)-L-III] showed a pronounced effect on the redox potentials. Different variants of Jahn-Teller distortion, axial elongation and compression, were observed in the Mn-III complexes.

• 出版日期2011