Biodegradable blends of urea plasticized thermoplastic starch (UTPS) and poly(epsilon-caprolactone) (PCL): Morphological, rheological, thermal and mechanical properties

作者：Correa Ana Carolina^*; Carmona Vitor Brait; Simao Jose Alexandre; Capparelli Mattoso Luiz Henrique; Marconcini Jose Manoel

来源：Carbohydrate Polymers, 2017, 167: 177-184.

DOI：10.1016/j.carbpol.2017.03.051

• UTPS
• PCL
• Polymer blends
• Rheology
• Morphology
• Mechanical properties
• Thermal analysis

Biodegradable blends of urea plasticized thermoplastic starch (UTPS) and poly(c-caprolactone) (PCL) were prepared in a co-rotating twin screw extruder. The UTPS and PCL content varied in a range of 25 wt%. The materials were characterized by capillary rheometry, scanning electron microscopy (SEM), termogravimetry (TGA), differential scanning calorimetry (DSC) and tensile tests. Capillary rheometry showed better interaction between UTPS and PCL at 110 degrees C than at 130 degrees C. SEM showed immiscibility of all blends and good dispersion of UTPS in PCL matrix up to 50 wt%. However, a co-continuous morphology was found for UTPS/PCL 75/25. Thermal analysis showed that introducing PCL in UTPS, increased To,,set due to higher thermal stability of PCL, and blends presented an intermediate behavior of neat polymers. The presence of PCL in blends improved significantly the mechanical properties of neat UTPS. Because they are totally biodegradable, these blends can be vehicles for controlled or slow release of nutrients to the soil while degraded.

• 出版日期2017-7-1