New polycyclic borazine species

作者：Xie Xiaochen; Haddow Mairi F; Mansell Stephen M; Norman Nicholas C^*; Russell Christopher A

来源：Chemical communications, 2011, 47(13): 3748-3750.

DOI：10.1039/c1cc10196j

The new polycyclic borazines B(2){1,2-N(2)C(6)H(4)}(2){B(2)(NMe(2))(2)}(2), B(2){1,8-N(2)naph}(2){B(2)(NMe(2))(2)}(2) and B(2)(NPh)(4){B(2)(NMe(2))(2)}(2) have been prepared from diborate(4) anions and two equivalents of B(2)Cl(2)(NMe(2))(2) and have been structurally characterised. Aspects of their structure and bonding are discussed and comparison made with corresponding polycyclic aromatic hydrocarbons.

• 出版日期2011