N ';-Benzoyl-N-tert-butyl-2-chloro-N ';-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}b enzohydrazide

作者:Shang Jian; Wang Qing min*; Huang Run qiu; Chen Li; Gao Jianhua
来源:Acta Crystallographica Section E-Structure Reports Online, 2009, 65(9): O2131-U1835.
DOI:10.1107/S1600536809028943

摘要

In the title compound, C(27)H(27)Cl(2)N(7)O(4)S, the amide groups bearing the N-S group and the tert-butyl group have s-trans conformations. The steric size of the tert-butyl and [(6-chloro-3-pyridyl)methyl]imidazolidin-2-ylidene groups cause the 2-chlorobenzoyl group and the benzyol group to be directed away from one another, forming a dihedral angle of 60.62 (17)degrees. The central N-N bond adopts a gauche conformation with a C-N-N-C torsion angle of -79.1 (2)degrees.

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