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摘要
A new two-dimensional (2D) manganese(II) coordination polymer {[Mn(bidc)(H2O)(2)]center dot 2H(2)O}(n) (H(2)bidc = benzimidazole-5,6-dicarboxylic acid) was synthesized, and characterized by X-ray crystallography and other measurements. The complex crystallizes in the orthorhombic system, space group Pbca with a = 7.0218(7), b = 17.9701(18), c = 19.0697(19) angstrom, V = 2406.3(4) angstrom(3), Z = 8, D-c = 1.823 g/cm(3), M-r = 330.14, F(000) = 1344, mu(MoK alpha) = 1.140 mm(-1), S = 1.055, R = 0.0305 and wR = 0.1012 for 2130 observed reflections (I > 2 sigma(I)). The title complex consists of a novel 2D network with a topology of short symbol (4.8(2))(4.8(2)).
- 出版日期2011-8-15
- 单位江苏理工学院
