Use of polymer as template in microwave synthesis of saponite. Study of several factors of influence

作者：Gebretsadik Fiseha B; Salagre Pilar^*; Cesteros Yolanda

来源：Applied Clay Science, 2014, 87: 170-178.

DOI：10.1016/j.clay.2013.10.027

• Saponite
• Template
• Mesoporous
• Delamination
• Microwave
• Slurry dilution

Several saponites were synthesized at pH = 8 by microwaves or conventional hydrothermal aging with different slurry dilutions (H2O/Si molar ratios of 250, 125 and 50) at 453 K under autogenic pressure. The influence of using a polymer as template, during the synthesis, and its molecular mass was investigated. The saponite prepared with medium dilution slurry by microwaves had the best incorporation of Al3+ in tetrahedral positions (Al-T/Al-O = 9.2), in agreement with its highest C.E.C. (0.87 mEq/g). Additionally, this sample showed the highest surface area (461 m(2)/g). In general, the increase of the slurry concentration and the presence of polymer improved the order in the tetrahedral sheet and decreased the amorphous silica content. The effect of polymer, on the stacking, was low but depended on the dilution and heat source (microwaves or conventional). The use of polymer and its molecular mass modified the saponite porosity and the incorporation of Al3+ in the tetrahedral sheet.

• 出版日期2014-1