Methylenecyclopropane as C1 synthetic units: [1+4] cycloaddition via a nickel catalyst

作者:Inami Tasuku; Kurahashi Takuya*; Matsubara Seijiro
来源:Chemical communications, 2011, 47(34): 9711-9713.
DOI:10.1039/c1cc13540f

摘要

Nickel-catalyzed reactions of methylenecyclopropanes and thioanhydrides afford sulfur-containing heterocyclic compounds via [1 + 4] cycloaddition. The reactions represent a new use for methylenecyclopropane as a possible one-carbon building block to replace carbon monoxide, isocyanides, and Fischer carbene complexes.

  • 出版日期2011