Adequacy of a stochastic model for choosing ligands for alloy electrodeposition from solutions of mixed-ligand and multivalent ion complexes

作者：Vinokurov E G^*; Bondar' V V

来源：Theoretical Foundations of Chemical Engineering, 2009, 43(3): 293-297.

DOI：10.1134/S0040579509030087

The adequacy of a stochastic model for choosing ligands which makes it possible to determine the regions of allowable values of the stability constants of complexes, the reduction of which occurs with the formation of an alloy, and choose ligands on the basis of these data is verified. Experimental data for alloy electrodeposition from solutions with complexes of different ligands and complexes of multivalent ions that are in published data show a good agreement with predictions by this model, which made it possible to formulate an important-for-practice condition of choosing ligands for joint reduction of complexes and the formation of an alloy.

• 出版日期2009-6
• 单位北京化工大学