A Multi-quaternary Ammonium Induced Synthesis of Bi2WO6 Sheet-Like Cluster Microspheres and Photoluminescence Properties

作者：Wei Xia; Zhou Yuan Lin^*; Li Yin Tao; Cheng Ya Fei

来源：Chinese Journal of Inorganic Chemistry, 2013, 29(3): 583-588.

DOI：10.3969/j.issn.1001-4861.2013.00.097

• Bi2WO6
• hydrothermal method
• cluster microspheres
• pH value
• photoluminescence

By using a Gemini quaternary ammonium as surfactant synthesized in laboratory and adjusting the different pH values, in this study, using the hydrothermal method, the different sheet-like cluster microspheres was self-assembled by Bi2WO6 nano-sheets. This study analyzed and characterized the effect of pH value on synthesis of Bi2WO6 sheet-like cluster microspheres, phase structure, composition, crystal morphology and photoluminescence properties, and explore its possible growth mechanism. The results show that different pH values caused a significant impact in Bi2WO6 sheet-like cluster microspheres phase structure, morphology and photoluminescence properties, when A multi-quaternary ammonium cationic dispersant as structure directing agents in the growth stage of Bi2WO6 Microspheres. With the increasing of pH value, sheet-like clusters Bi2WO6 microspheres showed obvious trend growth in the (131) direction, when pH=5, Bi2WO6 microspheres can reach a maximum luminous intensity.

• 出版日期2013-3-10
• 单位西南大学