A highly efficient Schiff-base derived palladium catalyst for the Suzuki-Miyaura reactions of aryl chlorides

作者：Shahnaz Nasifa; Banik Biplab; Das Pankaj^*

来源：Tetrahedron Letters, 2013, 54(22): 2886-2889.

DOI：10.1016/j.tetlet.2013.03.115

• Suzuki-Miyaura reaction
• Homogeneous catalysis
• Palladium complex
• Schiff-base ligand
• Aryl chloride

A new palladium complex derived from a bidentate Schiff-base ligand showed excellent activity as catalyst for the Suzuki-Miyaura cross-coupling reactions of less reactive aryl chlorides with arylboronic acids. Under an optimized condition, moderate-to-excellent yields of biaryls were obtained with a wide range of substrates at a relatively low loading of catalyst (0.2 mol %).

• 出版日期2013-5-29