Microstructure and optical limiting properties of multicomponent inorganic gel-glasses: A focus on SiO2, TiO2 and PbO gel-glasses

作者：Zheng Chan^*; Li Wei; Chen Wenzhe; Ye Xiaoyun; Cai Shuguang; Xiao Xueqing

来源：Ceramics International, 2014, 40(2): 2669-2675.

DOI：10.1016/j.ceramint.2013.10.057

• Sol-gel process
• Microstructure
• Optical limiting
• Nonlinear optical

Two kinds of multicomponent inorganic gel-glasses, namely, SiO2-TiO2 binary and SiO2-TiO2-PbO ternary gel-glasses, were obtained via the hydrolysis and co-condensation of tetraethyloxysilane (Si(OC2H5)(4), TEOS), titanium tetraisopropoxide (Ti(C4H9O)(4), TTIP), and lead (II) acetate trihydrate (Pb(Ac)(2)). X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, and pore structure measurements were performed to investigate the morphology, structure, and texture properties of the gel-glasses. The samples were mainly composed of amorphous phase without any detected phase separation. The introduced Ti4+ and Pb2+ were partially involved in the hydrolysis and condensation processes. Furthermore, the composition had a significant influence on the pore structure of silica-based gel-glasses, and the introduction of TiO2 in the gel-glasses caused the formation of bimodal-distributed pore shapes and dimensions in multicomponent inorganic gel-glasses. The optical limiting (OL) properties were measured at 532 nm by using the open aperture Z-scan technique. The SiO2-TiO2 binary and SiO2-TiO2-PbO ternary gel-glasses exhibited greatly enhanced OL behaviors than the SiO2 unitary gel-glass. The observed OL phenomenon in the SiO2-TiO2 binary gel-glass originated from two-photon absorption (TPA), whereas TPA followed by nonlinear scattering (NLS) contributed to the increased OL performance of the SiO2-TiO2-PbO ternary gel-glass. SiO2-TiO2 binary and SiO2-TiO2-PbO ternary gel-glasses are potential materials for practical applications in the fields of optics, all-optical switching, and related optical devices.

• 出版日期2014-3
• 单位福建工程学院