Microwave assisted reactions with gas reagents

作者:Petricci Elena*; Taddei Maurizio
来源:Chimica Oggi-Chemistry Today, 2008, 26(1): 18-22.

摘要

Controlled microwave heating has found many important applications in organic synthesis. Almost all kinds of reactions have been tested using microwaves. Major success in carrying out rapid organic transformations have been achieved when high temperatures are required and substrates or reagents do not survive to prolonged heating. On the other hand, very few reports deal with the use of gas as reagent inside a microwave oven, even though many organic transformations that employs gas are carried out under heating and could take advantage of the use of microwaves. This review collects all the contributions reported until now on microwave-assisted reaction using gas reagents. Expect for a few examples, all the reaction selected have been carried out under heating and could take advantage of the use of microwaves. This review collects all the reactions selected have been carried out using commercially available instruments for synthesis with minor modifications.

  • 出版日期2008-2