Direct growth of etch pit-free GaN crystals on few-layer graphene

作者:Chae Seung Jin; Kim Yong Hwan; Seo Tae Hoon; Duong Dinh Loc; Lee Seung Mi; Park Min Ho; Kim Eun Sung; Bae Jung Jun; Lee Si Young; Jeong Hyun; Suh Eun Kyung; Yang Cheol Woong; Jeong Mun Seok; Lee Young Hee*
来源:RSC Advances, 2015, 5(2): 1343-1349.
DOI:10.1039/c4ra12557f

摘要

We report high-quality GaN crystals grown directly on graphene layers without a buffer layer by metal-organic chemical vapour deposition. Photoluminescence and Raman spectra revealed that GaN crystals grown on graphene layers had mild strain as compared to those grown on sapphire and SiO2 substrates. Etch pits were not observed on the surface of GaN/graphene, in which threading dislocations were diminished inside the bulk. This is markedly different from GaN/sapphire, in which threading dislocations were present on GaN surfaces. This opens a new possibility that graphene with pi electrons and hexagonal symmetry could be an ideal substrate for GaN crystal growth instead of expensive sapphire substrates.

  • 出版日期2015