A new luminescent Pb(II) coordination polymer based on designed pyridinecarboxylate ligand

作者：Liu, Qifeng; Liu, Wei^*

来源：Inorganic and Nano-Metal Chemistry, 2017, 47(5): 768-771.

DOI：10.1080/15533174.2016.1212239

• Pb(II) compound
• 5-(pyridyl-4-ylmethoxy) isophthalic acid
• right-handed helical chain
• luminescence

A new Pb(II) compound, namely {Pb-2(L)(2)(H2O)(2)}(n) (1 H2L = 5-(pyridyl-4-ylmethoxy) isophthalic acid), has been synthesized by the reactions of Pb(II) ions and H2L. Single-crystal X-ray analysis reveals that compound 1 features a three-dimensional (3D) chiral framework based on 1D right-handed helical {Pb-2(COO)(2)}(n) chains. Moreover, the luminescent property of 1 was also investigated in the solid state at room temperature.

• 出版日期2017
• 单位河北农业大学